Application of Chemical Kinetics to Heterogeneous Systems |
Aharoni, C., D. L. Sparks, et al. 1991. Kinetics of soil chemical reactions: Relationships between empirical equations and diffusion models. Soil Sci. Soc. Am. J. 55: 1307-1312. |
Ogwada, R. A. and D. L. Sparks. 1986a. A critical evaluation on the use of kinetics for determining thermodynamics of ion exchange in soils. Soil Sci. Soc. Am. J. 50: 300-305. |
*Sparks, D. L. 1999. Kinetics and mechanisms of chemical reactions at the soil mineral/water interface. In D. L. Sparks (ed.) Soil Physical Chemistry, CRC Press, Boca Raton, FL |
Kinetic Methods |
*Amacher, M. C. 1991. Methods of obtaining and analyzing kinetic data. p. 19-59. In D. L. Sparks and D. L. Suarez (ed.) Rates of Soil Chemical Processes. SSSA Spec. Publ. No. 27. Soil Sci. Soc. Am., Madison, WI. |
Bar-Tal, A., D. L. Sparks, et al. 1990. Analyses of adsorption kinetics using a stirred-flow chamber: I. Theory and critical tests. Soil Sci. Soc. Am. J. 54: 1273-1278. |
Carski, T. H. and D. L. Sparks. 1985. A modified miscible displacement technique for investigating adsorption-desorption kinetics in soils. Soil Sci. Soc. Am. J. 49: 1114-1116. |
Fendorf, S. E., D. L. Sparks, et al. 1993. Electron paramagnetic resonance stopped-flow kinetic study of manganese (II) sorption-desorption on birnessite. Soil Sci. Soc. Am. J. 57: 57-62. |
Ogwada, R. A. and D. L. Sparks. 1986b. Kinetics of ion exchange on clay minerals and soil. I. Evaluation of methods. Soil Sci. Soc. Am. J. 50: 1158-1162. |
*Sparks, D. L. and P. C. Zhang. 1991. Relaxation methods for studying kinetics of soil chemical phenomena. p. 61-94. In D. L. Sparks and D. L. Suarez (ed.) Rates of Soil Chemical Processes. Soil Sci. Soc. Am. Spec. Publ. 27. Soil Sci. Soc. Am., Madison, WI. |
*Sparks, D. L., S. E. Fendorf, et al. 1996. Kinetic methods and measurements. p. 1275-1307. In D. L. Sparks (ed.) Methods of Soil Analysis: Chemical Methods Soil Sci. Soc. Am., Madison, WI. |
Sorption Kinetics |
Ainsworth, C. C., J. L. Pilou, et al. 1994. Cobalt, cadmium, and lead sorption to hydrous iron oxide: Residence time effect. Soil Sci. Soc. Am. J. 58: 1615-1623. |
*Alexander, M., 2000. Aging, bioavailability, and overestimation of risk from environmental pollutants. Environ. Sci. Technol., 34: 4259-4265. |
Arai, Y. and D.L. Sparks. 2002. Residence time effects on arsenate surface speciation at the aluminum oxide-water interface. Soil Sci. 167(5):303-314. |
Axe, L. and P. Trivedi. 2002. Intraparticle surface diffusion of metal contaminants and their attenuation in microporous amorphous Al, Fe and Mn oxides. J. Colloid Interf. Sci. 247:259-265. |
Backes, C. A., R. G. McLaren, et al. 1995. Kinetics of cadmium and cobalt desorption from iron and manganese oxides. Soil Sci. Soc. Am. J. 59: 778-785. |
Bruemmer, G. W., J. Gerth, et al. 1988. Reaction kinetics of the adsorption and desorption of nickel, zinc and cadmium by goethite: I. Adsorption and diffusion of metals. J. Soil Sci. 39: 37-52. |
Casey, W.H., B.L. Phillips, J.P. Nordin, and D.J. Sullivan. 1998. The rates of exchange of water molecules from Al(III)-methylmalonate complexes: The effect of chelate ring size. Geochim. Cosmochim. Acta 62:2789-2797. |
Comans, R. N. J. and D. E. Hockley. 1992. Kinetics of cesium sorption on illite. Geochim. Cosmochim. Acta 56: 1157-1164. |
| Dent, A.J. 2002. Development of time-resolved XAFS instrumentation for quick EXAFS and energy-dispersive EXAFS measurements on catalyst systems. Top. Catal. 18:27-35. |
Fendorf, S., M.J. La Force, and G. Li. 2004. Temporal changes in soil partitioning and bioaccessibility of arsenic, chromium, and lead. J. Environ. Qual. 33:2049-2055. |
Ford, R.G. 2002. Rates of hydrous ferric oxide crystallization and the influence on coprecipitated arsenate. Environ. Sci. Technol. 36:2459-2463. |
Giammar, D.E. and J.G. Hering. 2001. Time scales for sorption-desorption and surface precipitation of uranyl on goethite. Environ. Sci. Technol. 35:3332-3337. |
Glover, L.J., M.J. Eick and P.V. Brady. 2002. Desorption kinetics of cadmium2+ and lead2+ from goethite: Influence of time and organic acids. Soil Sci. Soc. Am. J. 66:797-804. |
| Gräfe, M., and D.L. Sparks. 2005. Kinetics of zinc and arsenate co-sorption at the goethite-water interface. Geochim. Cosmochim. Acta 69:4573-4595. |
Grossl, P. R., M.J. Eick, D. L. Sparks, S. Goldberg and C.C. Ainsworth. 1997. Arsenate and chromate retention mechanisms on goethite. 2. Kinetic evaluation using a pressure-jump relaxation technique. Environ. Sci. Technol 31:321-326. |
Grossl, P. R., D. L. Sparks, et al. 1994. Rapid kinetics of Cu (II) adsorption/desorption on goethite. Environ. Sci. Technol. 28: 1422-1429. |
Lee, A.P., B.L. Phillips and W.H. Casey. 2002. The kinetics of oxygen exchange between the GeO4A12(OH)24(OH2) 8+(aq) molecule and aqueous solutions. Geochim. Cosmochim. Acta 66(4):577-587. |
Lu, Y. and J.J. Pignatello. 2002. Demonstration of the “conditioning effect” in soil organic matter in support of a pore deformation mechanism for sorption hysteresis. Environ. Sci. Technol. 36:4553-4561. |
| Mifflin, A.L., K.A. Gerth, and F.M. Geiger. 2003. Kinetics of chromate adsorption and desorption at fused quartz/water interfaces studied by second harmonic generation. J Phys Chem A 107:9620-9627. |
Piatt, J.J., Backhus, D.A., Chapel, P.D. and Eisenreich, S.J., 1996. Temperature-dependent sorption of naphthalene, phenanthrene, and pyrene to low organic carbon aquifer sediments. Environ. Sci. Technol., 30: 751-760. |
*Pignatello, J. J. and B. Xing. 1996. Mechanisms of slow sorption of organic chemicals to natural particles. Environ. Sci. Technol. 30: 1-11. |
*Pignatello, J.J., 2000. The measurement and interpretation of sorption and desorption rates for organic compounds in soil media. In: D.L. Sparks (Editor), Advances in Agronomy. Academic Press, San Diego, pp. 1-73. |
Roberts, D.R., A.M. Scheidegger, and D.L. Sparks, 1999. Kinetics of mixed Ni-Al precipitate formation on a soil clay fraction. Environ. Sci. Technol., 33: 3749-3754. |
| Saffron, C.M. 2006. Kinetics of contaminant desorption from soil: Comparison of model formulations using the Akaike Information Criterion. Environ. Sci. Technol. 40:7662-7667. |
Scheidegger, A.M., G.M. Lamble, and D.L. Sparks, 1997. Spectroscopic evidence for the formation of mixed-cation, hydroxide phases upon metal sorption on clays and aluminum oxides. J. Colloid Interf. Sci., 186: 118-128. |
Scheidegger, A.M., D.G. Strawn, G.M. Lamble, and D.L. Sparks, 1998. The kinetics of mixed Ni-Al hydroxide formation on clay and aluminum oxide minerals: A time-resolved XAFS study. Geochimica Cosmochimica Acta., 62: 2233-2245. |
Scheinost, A.C., S. Abend, K.I. Pandya and D.L. Sparks. 2001. Kinetic controls of Cu and Pb sorption by ferrihydrite. Environ. Sci. Technol. 35:1090-1096. |
Steinberg, S. M., J. J. Pignatello, et al. 1987. Persistence of 1,2 dibromoethane in soils: Entrapment in intra particle micropores. Environ. Sci. Technol. 21: 1201-1208. |
Strawn, D.G., A.M. Scheidegger, and D.L. Sparks, 1998. Kinetics and mechanisms of Pb(II) sorption and desorption at the aluminum oxide-water interface. Environ. Sci. Technol., 32: 2596-2601. |
*Strawn, D.G. and Sparks, D.L., 1999. Sorption kinetics of trace elements in soils and soil materials. In: H.M. Selim and I. Iskandar (Editors), Fate and transport of heavy metals in the vandose zone. Lewis Publishers, Chelsea, MI, pp. 1-28 |
Strawn, D.G., and D.L. Sparks, 2000. Effects of soil organic matter on the kinetics and mechanisms of Pb(II) sorption and desorption in soil. Soil Sci. Soc. Am. J., 64: 144-156 |
| Villinski, J.E., P.A. O'Day, T.L. Corley, and M.H. Conklin. 1999. A flow-through cell for in situ, real time x-ray absorption spectroscopy studies of geochemical reactions, In Morganwalp, D.W. and Buxton, H.T., eds., U.S. Geological Survey Toxic Substances Hydrology Program Proceedings of the Technical Meeting, Charleston, South Carolina, March 8-12, 1999, Volume 1, Contamination from Hard Rock Mining: U.S. Geological Survey Water-Resources Investigations Report 99-4018A. |
Waltham, C.A. and M.J. Eick. 2002. Kinetics of arsenic adsorption on goethite in the presence of sorbed silicic acid. Soil Sci. Soc. Am. J. 66:818-825. |
Zhang, P. C. and D. L. Sparks. 1989. Kinetics and mechanisms of molybdate adsorption/desorption at the goethite/water interface using pressure-jump relaxation. Soil Sci. Soc. Am. J. 53: 1028-1034. |
Kinetics of Dissolution |
Bondiette, G., Sinniger, J. and Stumm, W., 1993. The reactivity of Fe(III) (hydr)oxides: Effects of ligands in inhibiting the dissolution. Colloids and Surf., 79: 157-167. |
Casey, W.H., and T.W. Swaddle. 2003. Why small? The use of small inorganic clusters to understand mineral surface and dissolution reactions in geochemistry. Rev. Geophysics 41:1008. |
Ford, R.G., A.C. Scheinost, K.G. Scheckel, and D.L. Sparks, 1999. The link between clay mineral weathering and the stabilization of Ni surface precipitates. Environ. Sci. Technol., 33: 3140-3144. |
Scheckel, K.G., A. C. Scheinost, R. G. Ford, and D. L. Sparks, 2000. Stability of layered Ni hydroxide surface precipitates - A dissolution kinetics study. Geochimica et Cosmochimica Acta, 64(16): 2727-2735. |
Scheckel, K.G. and D.L. Sparks. 2001. Dissolution kinetics of nickel surface precipitates on clay mineral and oxide surfaces. Soil Sci. Soc. Am. J. 65:685-694. |
Scheckel, K.G. and J.A. Ryan. 2002. Effects of aging and pH on dissolution kinetics and stability of chloropyromorphite. Environ. Sci. Technol. 36:2198-2204. |
Scheidegger, A. M. and D. L. Sparks. 1996. Kinetics of the formation and the dissolution of nickel surface precipitates on pyrophyllite. Chem. Geol. 132: 157-164. |
*Stumm, W. and R. Wollast. 1990. Coordination chemistry of weathering. Kinetics of the surface-controlled dissolution of oxide minerals. Rev. Geophys. 28: 53-69. |
White, A.F., and S.L. Brantley. 2003. The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field? Chem. Geol. 202:479-506. |
Redox Chemistry |
| Kim, J.G., and H.-S. Moon. 1998. Oxidation of chromium (III) to chromium (VI) by a series of synthesized birnessites (δ -MnO2): Kinetics and oxidation capacity. Clay Science 10:363-373. |
| Liu, C.X., B.H. Jeon, J.M. Zachara, Z.M. Wang, A. Dohnalkova, and J.K. Fredrickson. 2006. Kinetics of microbial reduction of solid phase U(VI). Environ. Sci. Technol. 40:6290-6296. |
Manning, B.A., S.E. Fendorf, B. Bostick and D.L. Suarez. 2002. Arsenic (III) oxidation and arsenic (V) adsorption reactions on synthetic birnessite. Environ. Sci. Technol. 36:976-981. |
Matocha, C.J., Sparks, D.L., Amonette, J.E. and Kukkadapu, R.K., 2001. Kinetics and mechanism of birnessite reduction by catechol. Soil Sci. Soc. Am. J., 65: 58-66. |
Nico, P.S. and R.J. Zasoki. 2001. Mn(III) center availability as a rate controlling factor in the oxidation of phenol and sulfide on σ-MnO2. Environ. Sci. Technol. 35:3338-3343. |
| Power, L.E., Y. Arai, and D.L. Sparks. 2005. Zinc adsorption effects on arsenite oxidation kinetics at the birnessite-water interface. Environ. Sci. Technol. 39:181-187. |
Scott, M.J. and Morgan, J.J., 1996. Reactions at oxide surfaces. 2. Oxidation of Se(IV) by synthetic birnessite. Environ. Sci. Technol., 30: 1990-1996. |
Stone, A.T., 1991. Oxidation and hydolysis of ionizable organic pollutants at hydrous metal oxide surfaces. In: D.L. Sparks and D.L. Suarez (Editors), Rates of Soil Chemical Processes. Soil Sci. Soc. Am., Madison, WI, pp. 231-254 |
Tournassat, C., L. Charlet, D. Bosbach and A. Manceau. 2002. Arsenic (III) oxidation of birnessite and precipitation of manganese (II) arsenate. Environ. Sci. Technol. 36:493-500. |
Weaver, R.M., M.F. Hochella, Jr. and E.S. Ilton. 2002. Dynamic processes occurring at the Cr III aq-manganite (γ-MnOOH) interface. Simultaneous adsorption, microprecipitation, oxidation/reduction and dissolution. Geochim. Cosmochim. Acta 66(23):4119-4132. |
| Weaver, R.M., and M.F. Hochella, Jr. 2003. The reactivity of seven Mn-oxides with Cr3+aq: A comparative analysis of a complex, environmentally important redox reaction. Am. Mineral. 88:2016-2027. |
Kinetic Models |
Carroll, K. M., M. R. Harkness, et al. 1994. Application of a permeant/polymer diffusional model to the desorption of polychlorinated biphenyls from Hudson River sediments. Environ. Sci. Technol. 28: 253-258. |
Connaughton, D. F., J. R. Stedinger, et al. 1993. Description of time-varying desorption kinetics: Release of naphthalene from contaminated soils. Environ. Sci. Technol. 27: 2397-2403. |
Pedit, J. A. and C. T. Miller. 1994. Heterogenous sorption processes in subsurface systems. 1. Model formations and applications. Environ. Sci. Technol. 28: 2094-2104. |
Weber, W. J., Jr., P. M. McGinley and L.E.Katz. 1992. A distributed reactivity model for sorption by soils and sediments: 1. Conceptual basis and equilibrium assessments. Environ. Sci. Technol. 26: 1955-1962. |
Wu, S. and P. M. Gschwend. 1986. Sorption kinetics of hydrophobic organic compounds to natural sediments and soils. Environ. Sci. Technol. 20: 717-725. |
| Zhang, H., and H.M. Selim. 2005. Kinetics of arsenate adsorption-desorption in soils. Environ. Sci. Technol. 39:6101-6108. |
| Zhang, H., and H.M. Selim. 2006. Modeling the transport and retention of arsenic (V) in soils. Soil Sci. Soc. Am. J. 70:1677-1687. |
* Review Papers |
