Environmental Soil Chemistry

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2013 Publications

Books Edited
Sparks, D.L. 2013. Editor, Advances in Agronomy. Vol. 118, Academic Press, San Diego, CA. Advancessm1a
Sparks, D.L. 2013. Editor, Advances in Agronomy. Vol. 119, Academic Press, San Diego, CA. Advancessm1a
Sparks, D.L. 2013. Editor, Advances in Agronomy. Vol. 120, Academic Press, San Diego, CA. Advancessm1a
Sparks, D.L. 2013. Editor, Advances in Agronomy. Vol. 121, Academic Press, San Diego, CA. 112
Sparks, D.L. 2013. Editor, Advances in Agronomy. Vol. 122, Academic Press, San Diego, CA. Advancessm1a
Xu, J. and D.L. Sparks. 2013. Editors, Molecular Environmental Soil Science. Springer, Dordrecht.

Chapters in Books

Sparks, D.L. 2013. Advances in the Use of Synchrotron Radiation
to Elucidate Environmental Interfacial Reaction Processes and Mechanisms in the Earth’s Critical Zone. In Molecular Environmental Soil Science. J. Xu and D.L. Sparks, eds. Pp. 93-114. Progress in Soil Science. Dordrecht: Springer.

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Refereed Publications

Agrawal, B., K. Czymmek, D.L. Sparks, and H.P. Bais. 2013. Transient influx of nickel in root mitochondria modulates organic acid and reactive oxygen species production in nickel hyperaccumulator Alyssum murale. J. Biol. Chem. 288(10):7351-7362.
DOI: 10.1074/jbc.M112.406645
DOI
Chimchart, B.,I. Kheoruenromne, A. Suddhiprakarn and D.L. Sparks. 2013. Role of organic matter on charge behavior of Oxisols and Ultisols under Tropical Savanna and Tropical Monsoon Climates in Thailand. Soil Sci. 178(10):540-549.
DOI: 10.1097/SS.0000000000000017
DOI
Lami, R., L.C. Jones, M. Cottrell, B. Lafferty, M. Ginder-Vogel, D.L. Sparks and D. Kirchman. 2013. Arsenite modifies structure of soil microbial communities and arsenite oxidization potential. FEMS Microbiology Ecology 84:270-279.
DOI: 10.1111/1574-6941.12061
DOI

Li, T. Z. Xua, X. Hana, X. Yanga and D. L. Sparks. 2013. Characterization of dissolved organic matter in the rhizosphere of hyperaccumulator Sedum alfredii and its effect on the mobility of zinc. Chemosphere 88 (5): 570–576.
DOI: 10.1016/j.chemosphere.2012.03.031

DOI

Li, T., Q. Tao, C. Liang, M.J.I. Shohag, X. Yang and D. L. Sparks. 2013. Complexation with dissolved organic matter and mobility control of heavy metals in the rhizosphere of hyperaccumulator Sedum alfredii. Environmental Pollution 182: 248-255.
DOI: 10.1016/j.envpol.2013.07.025

DOI

Li , W., Y. Wang, M. Zhu, T-T. Fan, D-M. Zhou, B. L. Phillips and D. L. Sparks. 2013. Inhibition mechanism of Zn precipitation on aluminum oxide by glyphosate: A 31P NMR and Zn EXAFS study. . Environ. Sci. Technol. 47(9):4211-4219.
DOI: 10.1021/es305120x

DOI

Li W., X. Feng, Y. Yan, D. L. Sparks, and B. L. Phillips. 2013. Solid state NMR spectroscopic study of phosphate sorption mechanisms on aluminum (hydr)oxides. Environ. Sci. Technol. 47 (15): 8308–8315.
DOI: 10.1021/es400874s

DOI
Shi, Z., D. M. Di Toro, H. E. Allen, and D. L. Sparks. 2013 .A general model for kinetics of heavy metal adsorption and desorption on soils. Environ. Sci. Technol.47(8):3761−3767.
DOI: 10.1021/es304524p

DOI

Thaymuang,W., I. Kheoruenromne, A. Suddhipraharn and D. L. Sparks. 2013 .The role of mineralogy in organic matter stabilization in tropical soils.Soil Science 178 (6), 1-8.
DOI: 10.1097/SS.0b013e3182a4dac4

DOI

Wang, X., F. Liu, W. Tan, W. Li, X. Feng and D. L. Sparks. 2013. Characteristics of phosphate sorption-desorption onto ferrihydrite: Comparison with crystalline Fe (hydro)oxides. Soil Science 178 (1), 1–11.
DOI: 10.1097/SS.0b013e31828683f8

DOI

Wang, X. , W. Li , R. Harrington , F. Liu , J. B. Parise , X. Feng and D. L. Sparks. 2013. Effect of ferrihydrite crystallite size on phosphate adsorption reactivity. Environ. Sci. Technol.47 (18): 10322–10331.
DOI: 10.1021/es401301z

DOI
Invited Presentations
Sparks, D.L. 2013. The Role of Metal Redox Coupling Processes in Carbon and Arsenic Cycling in the Critical Zone, Department of Soil Science, University of Wisconsin, Madison, WI, March 6.  
Sparks, D.L. 2013. Grand Challenges in Environmental Sustainability: The Water, Climate, Soil, and Food Nexus, Weston Roundtable Series, University of Wisconsin, Madison, WI, March 7.  
Sparks, D.L. 2013. Time-Resolved Metal(loid) Reactivity at Biogeochemical Interfaces: Impacts on Cycling and Sequestration, Department of Civil and Environmental Engineering, University of Wisconsin, Madison, WI, March 8.  
Sparks, D.L. 2013. The Role of Metal Redox Coupling Processes in Carbon and Arsenic Cycling in the Critical Zone. Department of Soil Science, Kasetsart University, Bangkok, Thailand. March 26.  
Sparks, D.L. 2013. Grand Challenges in Environmental Sustainability: The Water, Climate, Soil, and Food Nexus. Faculty of Agriculture, Kasetsart University, Bangkok, Thailand. March 28.  

Sparks, D.L. 2013. Surface Precipitation Mechanisms and their role in Metal Sequestration in Natural Environments. 245th American Chemical Society National Meeting and Exposition, New Orleans, Louisiana. April 7-11.

abstract
Sparks, D.L. 2013. Shining Light on Environmental Biogeochemical Processes: The Role of Synchrotron Radiation. Institute of Soil Science, Nanjing, China. April 20.  
Sparks, D.L. 2013. Soil and Environmental Sustainability: Research Challenges and Opportunities. Nanjing Agricultural University, Nanjing, China. April 22.  
Sparks, D.L. 2013. The Role of Mineral Complexation and Redox Cycling on Carbon Sequestration in the Earth’s Critical Zone.  Critical Zone Processes and Their Effects on Climatic, Ecological, and Environmental Changes Workshop, Nanjing, China. April 23-25.  
Sparks, D.L. 2013.  Grand Challenges in Environmental Sustainability: The Water, Climate, Soil, and Food Nexus. Northwest Agriculture University, Yangling, China. April 26.  

Sparks, D.L. and C. Chen. 2013. Shedding Light on Carbon-mineral Complexation in the Soil Environment: Impacts on C Sequestration and Cycling. International Union of Soil Sciences, Madison, Wisconsin. June 3-6.

abstract
Sparks, D.L. 2013. C-mineral Complexation and its Role on C Cycling and Sequestration. XXXIV Brazilian Congress of Soil Sciences, Florianopolis, Brazil, July 28-August 2.  
Sparks, D.L. 2013. Grand Challenges and Opportunities in Soil Chemistry in the 21st Century.  XXXIV Brazilian Congress of Soil Sciences, Florianopolis, Brazil, July 28-August 2.  
Sparks, D.L. 2013. Shining Light on Soil Biogeochemical Processes: Opportunities and Challenges in the 21st Century, German Soil Science Society Meeting, Rostock, Germany, Sept. 7-12.  
Sparks, D.L. 2013. The Role of Mineral Complexation and Metal Redox Coupling in Carbon Cycling and Stabilization. Soil Science Department, University of Wisconsin, Madison, October 23.  
Sparks, D.L. 2013. Grand Challenges in Environmental Sustainability: The Climate, Water, Soil, and Food Nexus. Weston Distinguished Lecturer, University of Wisconsin, Madison, October 24.  
Sparks, D.L. 2013. Grand Challenges and Opportunities in Environmental Sustainability: The Soil, Water, Climate, and Food Nexus, Osher Institute of Lifelong Learning, Wilmington, DE, Nov. 11.  
Sparks, D.L. 2013. Grand Challenges and Opportunities in Environmental Sustainability: The Soil, Water, Climate, and Food Nexus, University of Massachusetts, Stockbridge School of Agriculture , Amherst, MA, , Nov. 18.  
Sparks, D.L. 2013. Assessment of Metal Cycling and Speciation in Delaware Contaminated Soils. Workshop on Sea Level Rise and Contaminated Soils, University of Delaware, Newark, DE, Nov. 22.  

Presentations

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Chen, C. and D. L. Sparks. 2013. Effect of Ferrihydrite-organic Matter Coprecipitation on the Fe(II)-catalyzed Transformation of Ferrihydrite. 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana, April 7-11. abstract
Chen, C., J. J. Dynes, J. Wang, T. Regier and D. L. Sparks. 2013. Mechanisms of Ferrihydrite-organic Matter Complex Formation via Adsorption and Coprecipitation. 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana, April 7-11. abstract
Feng, X., W. Li, M. Zhu, P. Northrup, and D. L. Sparks. 2013. Sorption Mechanism of Myoinositol Hexaphosphate on Boehmite: A 31P NMR and P EXAFS Study. 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana, April 7-11. abstract
Ginder-Vogel, M., B. Lafferty and D.L. Sparks. 2013. As(III) Oxidation by Hydrous Manganese(IV) oxide: Kinetics, Mechanisms, and Inhibition. 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana, April 7-11. abstract
Lazareva, O., D. L. Sparks, R. Landis, N.R. Grosso, J. Collins, J. A. Dyer, C.J. Ptacek, S. Hicks and D. Montgomery. 2013. Understanding Biogeochemical Transformation And Mobilization Of Hg From River Bank Soils: South River, Virginia. Goldschmidt 2013, Florence, Italy, August 25-30. PDF
Lazareva, O.,D. L. Sparks, R. Landis, C.J. Ptacek, J. Ma, J. A. Dyer, N.R. Grosso, S. Hicks, and D. Montgomery 2013. A Coupled Monitoring Network To Conduct An Assessment Of Mercury Transformation And Mobilization In Floodplain Soils: South River, Virginia. AGU Fall Meeting, San Francisco, Dec 9-13. PDF
Li, W., X. Feng, P. Northrup, J. D. Kubicki and D. L. Sparks. 2013. Glyphosate Sorption Mechanism at the Boehmite/Water Interface Using Solid State 31P NMR and P XANES. 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana, April 7-11. abstract
Li, W. M. Zhu, and D. L. Sparks. 2013. Advances in Understanding the Chemistry of Light Elements at Environmental Interfaces (Symposium). 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana,  April 7-11.  
Li, W., M. Siebecker, K. Syed, and D. L. Sparks, 2013. Kinetics of Ni-Al Layer Double Hydroxide Precipitate Formation on Aluminum Oxide: A Time-resolved XRD and Quick-scanning EXAFS Study. Soil Science Society of America (SSSA) International Annual Meeting, Tampa, FL, Nov 3-7. abstract
Northrup, P. and D. L. Sparks. 2013. Advances in Spatially-resolved Tender-energy X-ray Absorption Spectroscopy at NSLS and NSLS-II. 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana, April 7-11. abstract
Siebecker, M., W. Li, S. Khalid and D. L. Sparks. 2013. Real-time Sorption and Precipitation of Nickel on Clay Minerals: An in situ Quick-EXAFS Investigation. 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana, April 7-11. abstract
Zhu, M., P. Northrup, D. L. Sparks and G. A. Waychunas. 2013. Sulfate Adsorption on Ferrihydrite Studied by Sulfur K-edge EXAFS Spectroscopy and Differential PDF Analyses. 245th American Chemical Society National Meeting & Exposition, New Orleans, Louisiana, April 7-11. abstract

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